Learning Resources for Microsoft SQL Server 2005
http://www.microsoft.com/technet/prodtechnol/sql/2005/learning/default.mspx
* look for "free eLearning series" lower down the page
Great ASP.NET 2.0 Tutorial Videos Online
http://weblogs.asp.net/scottgu/archive/2006/02/26/439088.aspx
* lots of nice links to free videos on different ASP.NET topics
Microsoft ASP.NET 2.0 Webcast Series
http://www.learn2asp.net/Campaign.aspx
* free webcasts targetted at current JSP, PHP, or ColdFusion developers
VisualStudio.NET 2005 - The Difference is Obvious.
http://www.thedifferenceisobviousvb05.com