MOC 10961: Automating Administration with Windows PowerShell
http://www.microsoft.com/learning/en/us/course.aspx?id=10961a&locale=en-us#fbid=9CMopxdy0_L
I just learned about this awesome course, written by Don Jones, that is available to MCTs this month.
The course looks to be a good beginners look at PowerShell V3. As the Microsoft web site points out, this will be a 200-level course and is not intended to teach hardcore scripting or programming.
For IT pros who have never seen PowerShell, this looks to be a very good course, although it doesn't appear to be extremely technical.