Silverlight and Blend tutorials
Here is a great new website for you "expression-scary developers" :
http://www.nibblestutorials.net/
It provides tutorials on how to build rich web experiences and applications using Silverlight and Blend.
Each tutorial is a very simple step-by-step so don't be afraid to test your designer skills...
Note that the website itself and tutorials are entirely done with Silverlight by Celso Gomes, one of the top design engineers in Redmond.